Poster Presentation
Biography
Sarinthip Thanakkasaranee has completed her Master of Science in Packaging Technology from Kasetsart University, Thailand. During her M.Sc., degree, she has received research grant under “The Thailand Research Fund - Master Research Grants (TRF-MAG) Window I†from Thailand Research Fund in 2011. She also won outstanding Master’s thesis award in the discipline of physical science, and the excellent student award in the Master's degree program from Kasetsart University in 2012. She had worked in the position of Product Development Executive, SML (Thailand) Co., Ltd. and Innovation Designer and Coordinator, Science and Technology Park, Chiang Mai University (CMU STeP). Now, she is doing Ph.D under a guidance of Prof. Jongchul Seo in the Department of Packaging, Yonsei University, South Korea. She also received the Outstanding Foreign Student Scholarship for her Ph.D. program.She has published 2 research papers in peer-reviewed International Journals and also presented her 4 (2 oral, 2 poster) research results in International Conferences
Abstract
The microwave markets are expected to witness remarkable growth fueled by consumer demands due to the need for the ease of preparation and portability to consume on the go. Th e critical problems of microwave cooking are expansion of internal pressure, explosion of package, and migration of chemical compound from the package into the food product during cooking. Th is issue can be solved by improving the packaging materials and design such as a weak heat seal, shrink-film covered vent valves, and laser scored or perforated fi lm. However, multiple processes are required to produce such packages,which lead to relatively high production cost. In this study, it is proposed to develop polymer/phase change materials (PCM) films with temperature responsive gas permeability as packaging materials as it have the characteristic of self ventilation and applicable to use in microwave oven by preventing the damages and explosion of packaging during the cooking process. A series of poly (ether-block-amide)/polyethylene glycol (PEBAX/PEG) composite fi lms are prepared by solution casting technique. Th e permeation properties, morphologies, thermal properties, and water sorption are interpreted as a function of PEG with diff erent molecular weights. Th e low molecular weight PEGs (PEG 950-1050 and PEG 3350) are well dispersed in the PEBAX matrix, whereas phase separation and surface roughness occurred by adding high molecular weight PEG (PEG 35000) into PEBAX matrix. Th e phase change and gas permeation property of composite fi lms are signifi cantly dependent on the molecular weight of PEGs. Incorporation of low molecular weight PEGs into PEBAX matrix showed a lower oxygen transmission rate (OTR) than pure PEBAX fi lms in the measured temperature ranged from 10°C to a relatively low melting temperatures of each PEGs, which is due to good interaction between PEBAX and PEGs, and an increase in crystallinity of the composite fi lm by introducing PEGs. As the measurement temperature is increased from the melting temperatures of each PEGs to 80°C, the OTR of composite fi lms dramatically increased. Th e composite films exhibited permeation jumps that occur at the melting point of crystallized phase depending on the molecular weight of PEGs. Th e composite film incorporated with high molecular weight PEG exhibited highest permeation jump.
Biography
Wei is now pursuing his PhD at the department of applied biology and chemical technology,the Hong Kong Polytechnic University. He is involved in projects related to photocatalysis, semiconductor material and nanotechnology.He has published 5 papers in reputed journals such as J. Phys. Chem.C, Electrochim. Acta, J. Chin. Polym. Sci., Sci. China Chem., Sci. Rep., etc.
Abstract
Hydrogen energy presents an ideal alternative to fossil fuels in the future because of its high energy capacity, environmental friendliness, and cost-effectiveness. To date, much attention has been devoted to one-dimensional (1D) semiconductor nanomaterials for hydrogen generation due to its stability, catalytic activity and simple fabrication. 1D semiconductor material such as TiO2 nanotube (TNT) shows potential as a solar photocatalyst for hydrogen generation by its large surface area and superior charge transport property. However, some problems such as large band gap (3.3-3.8 eV) and high recombination rate of the photogenerated electron–hole pairs limits the solar application of TiO2. Particularly, TNTs decoration with sensitizer offers an effective way to improve the photocatalytic activity for solar application by extending the photo-response and promoting the separation of photogenerated electron-hole pairs. Recently, using copper sulfide (CuxS) has emerged as an effective sensitizer for improving hydrogen evolution reaction. The copper sulfide family offers a wide spectrum of derivatives and attractive due to their wide absorption band and low reflectance in the visible range, making it a prime candidate for solar energy-harvesting. The CuxS nanodots (NDs) onto the surface of TNTs is elaborately investigated on the morphologies, phase, and optical properties as well as the photocatalytic behavior of the CuxS/TNT. The results demonstrated that the CuxS ND/TNT is an excellent photocatalyst for efficient and stable hydrogen generation from water without noble metal co-catalysts